Energy Innovation Lab: Publications
Publications
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Layered LnBaCo2O5+δ Perovskite Cathodes for Solid Oxide Fuel Cells: An Overview and Perspective
J.-H. Kim and A. Manthiram*
Journal of Materials Chemistry A, 3, 24195-24210 (2015). -
Challenges and Approaches for High Voltage Spinel Li-Ion Batteries
J.-H. Kim*, N. P. W. Pieczonka, Li Yang
ChemPhysChem, 15, 1940-1954 (2014). -
Crystal chemistry and properties of Mixed Ionic-Electronic Conductors
A. Manthiram*, J.-H. Kim, Y. N. Kim, and K.-T. Lee
Journal of Electroceramics, 27, 93-107 (2011).
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Multi-Functional Composite Binder for High-Voltage Lithium-Ion Batteries
L. Rao, C.-Y. Yu, A. Schmidt, C. O’Meara, J. Seidt, J. R. Sayre, J.-H. Kim*
(under review) -
Relationship of Chemical Composition and Moisture Sensitivity in LiNixMnyCo1-x-yO2 for Lithium-Ion Batteries
J. Choi, L. Dong, C.-Y. Yu, C. O’Meara, E. Lee, J.-H. Kim*
ASME Journal of Electrochemical Energy Conversion and Storage (in press) -
Comprehensive Electrochemical Impedance Spectroscopy Study of Si-Based Anodes Using Distribution of Relaxation Times Analysis
K. Pan, F. Zou, M. Canova*, Y. Zhu, J.-H. Kim*
Journal of Power Sources, 479, 229083 (2020). -
In Operando AFM Characterization of Mechanical Property Evolution of Si Anode Binders in Liquid Electrolyte
M. Lee, R. Reddi, J. Choi, J. Liu, X. Huang*, H. Cho*, and J.-H. Kim
ACS Applied Energy Materials, 3, 1899-1907 (2020). -
High Temperature Chemical Stability of Li1.4Al0.4Ti1.6(PO4)3 Solid Electrolyte with Various Cathode Materials for Solid-State Batteries
C.-Y. Yu, J. Choi, V. Anandan, J.-H. Kim*
ACS Applied Energy Materials, 3, 1899-1907 (2020). -
Comprehensive Electrochemical Impedance Spectroscopy Study of Si-Based Anodes Using Distribution of Relaxation Times Analysis
K. Pan, F. Zou, M. Canova*, Y. Zhu, J.-H. Kim*
Journal of Power Sources, 479, 229083 (2020). -
Calibration of Electrochemical Models for Li-ion Battery Cells Using Three-Electrode Testing
P. Brodsky, M. Canova, J.-H. Kim, P. Ramesh, C. Bae, J. Deng, H. Park.
SAE Technical Paper, 2020-01-1184, (2020). -
Deciphering the Oxygen Absorption Pre‐Edge: A Caveat on its Application for Probing Oxygen Redox Reactions in Batteries
S. Roychoudhury, R. Qiao, Z. Zhuo, Q. Li, Y. Lyu, J.-H. Kim, J. Liu, E. Lee, B. J. Polzin, J. Guo, S. Yan, Y. Hu, H. Li, D. Prendergast, W. Yang
Energy & Environmental Materials, 0, 1-9 (2020). -
Nickel-Salen Type Polymer as Conducting Agent and Binder for Carbon-Free Cathodes in Lithium-Ion Batteries
C. O'Meara, M. P. Karushev, I. A. Polozhentceva, S. Dharmasena, H. Cho, B. J. Yurkovich, S. Kogan, J.-H. Kim*
ACS Applied Materials & Interfaces, 11, 525-533 (2019). -
Systematic Electrochemical Characterizations of Si and SiO Anodes for High-Capacity Li-Ion Batteries
K. Pan, F. Zou, M. Canova*, Y. Zhu, J.-H. Kim*
Journal of Power Sources, 413, 20-28 (2019). -
Lithium Poly-Acrylate (LiPAA) as an Advanced Binder and Passivating Agent for High Voltage Li-Ion Batteries
N. P. W. Pieczonka, V. Borgel, B. Ziv, N. Leifer, V. Dargel, D. Aurbach*, J.-H. Kim*, Z. Liu, X. Huang, S. A. Krachkovskiy, G. R. Goward, I. Halalay, B. R. Powell, A. Manthiram
Advanced Energy Materials, 5(23), 1501008 (2015). -
In-Situ Formation of Cathode Electrolyte Interface with Enhanced Stability by Titanium Substitution for High Voltage Spinel Lithium-Ion Batteries
J.-H. Kim*, N. P. W. Pieczonka, P. Lu, Z. Liu, R. Qiao, W. Yang, M. M. Tessema, Y.-K. Sun*
Advanced Materials Interfaces, 2(10), 1500109 (2015). -
New Chemical Route for the Synthesis of β-Na0.33V2O5 and Its Fully Reversible Li Intercalation
J.-K. Kim, B. Senthilkumar, S. H. Sahgong, J.-H. Kim*, M. Chi, Y. Kim
ACS Applied Materials & Interfaces, 7, 7025-7032 (2015). -
The LiZnxNi0.5-xMn1.5O4 spinel with improved high voltage stability for Li-ion batteries
Z. Yang, Y. Jiang, J.-H. Kim, Y. Wu, Y.-H. Huang*
Electrochimica Acta, 117, 76-84 (2014). -
Improved Lithium-Ion Battery Performances of LiNi0.5Mn1.5-xTixO4 High Voltage Spinel in Full-Cells Paired with Graphite and Li4Ti5O12 Negative Electrodes
J.-H. Kim*, N. P. W. Pieczonka, Y.-K. Sun, Bob. R. Powell
Journal of Power Sources, 262, 62-71 (2014). -
Integrated Nano-Domains of Disordered and Ordered Spinel Phases in LiNi0.5Mn1.5O4 for Li-Ion Batteries
J.-H. Kim*, A. Hug, M. Chi, N. P. W. Pieczonka, E. Lee, C. A. Bridges, M. M. Tessema, A. Manthiram, K. A. Persson, B. R. Powell
Chemistry of Materials, 26, 4377-4386 (2014). -
Investigation of the reasons for capacity fading in Li-ion battery cells
B. Ziv, V. Borgel, D. Aurbach*, B. R. Powell, J.-H. Kim, and X. Xiao
Journal of the Electrochemical Society, 161, A1672-A1680 (2014). -
Understanding Capacity Fading Mechanism in LiNi0.5Mn1.5O4/Graphite Li-Ion Batteries
J.-H. Kim*, N. P. W. Pieczonka, Z. Li, Y. Wu, S. Harris, B. R. Powell
Electrochimica Acta, 90, 556-562 (2013). -
Understanding Transition Metal Dissolution Behavior in LiNi0.5Mn1.5O4 High Voltage Spinel for Li-Ion Batteries
N. P. W. Pieczonka, Z. Liu, P. Lu, K. L. Olson, J. Moote, B. R. Powell, J.-H. Kim*
Journal of Physical Chemistry C, 117, 15947-15957 (2013). -
Impact of Lithium Bis-Oxalate Borate Electrolyte Additive on the Performance of High-Voltage Spinel/Graphite Li-Ion Batteries
N. P. W. Pieczonka, L. Yang, M. P. Balogh, B. R. Powell, K. Chemelewski, A. Manthiram, S. A. Krachkovskiy, G. R. Goward, M. Liu, J.-H. Kim*
Journal of Physical Chemistry C, 117, 22603−22612 (2013). -
Comparative Study of LiMnPO4/C Cathodes Synthesized by Polyol and Solid-State Reaction Methods for Li-Ion Batteries
N. P. W. Pieczonka, Z. Liu, A. Huq, J.-H. Kim*
Journal of Power Sources, 230, 122-129 (2013). -
Multilayer electrolyte cell: a new tool for identifying electrochemical performances of high voltage cathode materials
N. M. Asl, J.-H. Kim*, N. P. W. Pieczonka, Z. Liu, Y. Kim*
Electrochemistry Communications, 32, 1-4 (2013) -
Atomic Layer Coating to Mitigate Capacity Fading Associated with Manganese Dissolution in Lithium Ion Batteries
X. Xiao*, D. Ahn, Z. Liu, J.-H. Kim, P. Lu
Electrochemistry Communications, 32, 31-34 (2013). -
A New Chemical Route for the Synthesis of β'-LixV2O5 for Use as a High Performance Cathode
N. M. Asl, J.-H. Kim*, W. C. Lee, Z. Liu, P. Lu, Y. Kim*
Electrochimica Acta, 105, 403-411 (2013). -
Microscale core-shell structured Li[(Ni0.8Co0.1Mn0.1)0.8(Ni0.5Mn0.5)0.2]O2 as positive electrode material for lithium batteries
Y.-K. Sun*, S.-T. Myung, M.-H. Kim, and J.-H. Kim
Electrochemical and Solid-State Letters, 9 (3), A171-A174 (2006). -
Improvement of electrochemical properties of LiNi0.5Mn1.5O4 spinel material by fluorine substitution
S.-W. Oh, S.-H. Park, J.-H. Kim, Y. C. Bae, and Y.-K. Sun*
Journal of Power Sources, 157 (1), 464-470 (2006). -
XAS investigation of inhomogeneous metal-oxygen bond covalency in bulk and surface for charge compensation in Li-ion battery cathode Li[Mn1/3Co1/3Ni1/3]O2 material
M.-G. Kim, H.-J. Shin, J.-H. Kim, S.-H. Park, and Y.-K. Sun*
Journal of the Electrochemical Society, 152 (7), A1320-A1328 (2005). -
The effect of Al(OH)3 coating on the Li[Li0.2Ni0.2Mn0.6]O2 cathode material for lithium secondary battery
Y.-J. Kang, J.-H. Kim, S.-W. Lee, and Y.-K. Sun*
Electrochimica Acta, 50 (24), 4784-4791 (2005). -
Improvement of high voltage cycling behavior of surface-modified Li[Ni1/3Co1/3Mn1/3]O2 cathode by fluorine substitution for Li-ion battery
G.-H Kim, J.-H. Kim, C. S. Yoon, S.-T. Myung, and Y.-K Sun*
Journal of the Electrochemical Society, 152 (9), A1707-A1713 (2005). -
Structural and electrochemical study of Li-Al-Mn-O-F spinel material for lithium secondary batteries
Y.-J. Kang, J.-H. Kim, and Y.-K. Sun*
Journal of Power Sources, 146 (1-2), 237-240 (2005). -
Comparative study of LiNi0.5Mn1.5O4-δ and LiNi0.5Mn1.5O4 cathodes having two crystallographic structures: Fd-3m and P4332
J.-H. Kim, S.-T. Myung, C.S. Yoon, S.G. Kang, and Y.-K. Sun*
Chemistry of Materials, 16 (5), 906-914 (2004). -
Molten salt synthesis of LiNi0.5Mn1.5O4 spinel for 5 V class cathode material of Li-ion secondary battery
J.-H. Kim, S.-T. Myung, and Y.-K. Sun*
Electrochimica Acta, 49 (2), 219-227 (2004). -
Phase Transitions in Li1-δNi0.5Mn1.5O4 during cycling at 5 V
J.-H. Kim, C.S. Yoon, S.-T. Myung, Jai Prakash, and Y.-K. Sun*
Electrochemical and Solid-State Letters, 7 (7), A216-A220 (2004). -
Effect of Ti Substitution for Mn on the Structure and Electrochemical Properties of LiNi0.5Mn1.5-xTixO4 Cathode Material
J.-H. Kim, S.-T. Myung, C. S. Yoon, and Y.-K. Sun*
Journal of the Electrochemical Society, 151 (11), A1911-A1918 (2004). -
Structural Characterization of Li[Li0.1Ni0.35Mn0.55]O2 Cathode Material for Lithium Secondary Batteries
J.-H. Kim, C.S. Yoon, and Y.-K. Sun*
Journal of the Electrochemical Society, 150 (4), A538-A542 (2003). -
Electrochemical performance of Li[LixNi(1-3x)/2Mn(1+x)/2]O2 cathode materials synthesized by a sol-gel method
J.-H. Kim and Y.-K. Sun*
Journal of Power Sources, 119, 166-170 (2003). -
Synthesis and electrochemical behavior of Li[Li0.1Ni0.35-x/2CoxMn0.55-x/2]O2 cathode materials
J.-H. Kim, C.W. Park, and Y.-K. Sun*
Solid State Ionics, 164 (1-2), 43-49 (2003). -
Direct experimental probe of the Ni(II)/Ni(III)/Ni(IV) redox evolution in LiNi0.5Mn1.5O4 electrodes
R. Qiao, A. Wray, J.-H. Kim, N. P. W. Pieczonka, S. Harris, W. Yang*
Journal of Physical Chemistry C, 119 , 27228–27233 (2015).
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Visualizing Oxygen Anion Transport Pathways in NdBaCo2O5+δ by in-situ Neutron Diffraction
R. Cox-Galhotra, A. Huq, J. P. Hodges, J.-H. Kim, C. Yu, X. Wang, A. J. Jacobson, and S. McIntosh*
Journal of Materials Chemistry A, 1, 3091-3100 (2013). -
Overcoming phase instability of RBaCo2O5+δ (R = Y and Ho) by Sr substitution for application as cathodes in solid oxide fuel cells
J.-H. Kim, Y. N. Kim, Z. Bi, A. Manthiram, M. P. Paranthaman, A. Huq*
Solid State Ionics, 253, 81-87 (2013). -
(Y0.5In0.5)Ba(Co,Zn)4O7 cathodes with superior high-temperature phase stability for solid oxide fuel cells
Y. N. Kim, J.-H. Kim, A. Huq, M. P. Paranthaman, and A. Manthiram*
Journal of Power Sources, 214, 7-14 (2012). -
Effect of Ca Doping on the Electrical Conductivity of the High-Temperature Proton Conductor LaNbO4
Z. Bi, J. Pena-Martinez, J.-H. Kim, C. A. Bridges, A. Huq, J. Hodges, and M. P. Paranthaman*
International Journal of Hydrogen Energy, 37, 12751–12759 (2012). -
Crystal Chemistry and Electrochemical Properties of LnSr3(Fe,Co)3O10 Intergrowth Oxide Cathodes for Solid Oxide Fuel Cells
J.-H. Kim, K.-T. Lee, Y. N. Kim, and A. Manthiram*
Journal of Materials Chemistry, 21, 2482-2488 (2011). -
High temperature phase stabilities and electrochemical properties of InBaCo4-xZnxO7 cathodes for intermediate temperature solid oxide fuel cells
J.-H. Kim, Y. N. Kim, Z. Bi, A. Manthiram, M. P. Paranthaman, A. Huq*
Electrochimica Acta, 56, 5740-5745 (2011). -
Phase Stability and Electrical Conductivity of Ca-doped LaNb1-xTaxO4-δ high temperature proton conductors
Z. Bi, C. A. Bridges, J.-H. Kim, A. Huq, and M. P. Paranthaman*
Journal of Power Sources, 196, 7395-7403 (2011). -
Effects of Ga Substitution on the High Temperature Properties of the n = 3 Ruddlesden Popper System LaSr3Fe1.5-x/2Co1.5-x/2GaxO10-δ (0 ≤ x ≤ 0.8)
F. Prado, J.-H. Kim, and A. Manthiram*
Solid State Ionics, 192, 241-244 (2011). -
Microstructural and Electrical Properties of Ce0.9Gd0.1O1.95 (GDC) Thin Film Electrolyte in Solid Oxide Fuel Cells
S. Cho, J. Yoon, J.-H. Kim, X. Zhang, A. Manthiram, and H. Wang*
Journal of Materials Research, 26, 854-859 (2011). -
Characterization of (Y1-xCax)BaCo4-yZnyO7 as cathodes for intermediate temperature solid oxide fuel cells
Y. N. Kim, J.-H. Kim, and A. Manthiram*
International Journal of Hydrogen Energy, 36, 15295-15303 (2011). -
High power density thin film SOFCs with YSZ/GDC bilayer electrolyte
S. M. Cho, Y. N. Kim, J.-H. Kim, A. Manthiram, and H. Wang*
Electrochimica Acta, 56, 5472-5477 (2011). -
Electrochemical characterization of YBaCo3ZnO7 + Gd0.2Ce0.8O1.9 composite cathode for intermediate temperature solid oxide fuel cells
J.-H. Kim, Y. N. Kim, S. M. Cho, H. Wang, and A. Manthiram*
Electrochimica Acta, 55, 5312-5317 (2010). -
Effect of Fe substitution on the structure and properties of LnBaCo2-xFexO5+δ (Ln = Nd and Gd) cathodes
Y. N. Kim, J.-H. Kim, and A. Manthiram*
Journal of Power Sources, 195, 6411-6419 (2010). -
Low Thermal Expansion RBa(Co,M)4O7 Cathode Materials Based on Tetrahedral-site Cobalt Ions for Solid Oxide Fuel Cells
J.-H. Kim and A. Manthiram*
Chemistry of Materials, 22, 822-831 (2010). -
Vertically aligned nanocomposite thin films as a cathode-electrolyte interface layer for thin film solid oxide fuel cells
S. Cho, J. Yoon, J.-H. Kim, J. H. Lee, Z. Bi, A. Serquis, X. Zhang, A. Manthiram, and H. Wang*
Advanced Functional Materials, 19 (24), 3868-3873 (2009). -
Layered NdBaCo2-xNixO5+δ perovskite oxides as cathodes for intermediate temperature solid oxide fuel cells
J.-H. Kim and A. Manthiram*
Electrochimica Acta, 54, 7551-7557 (2009). -
Characterization of Sr2.7Ln0.3Fe1.4Co0.6O7 (Ln = La, Nd, Sm, Gd) intergrowth oxides as cathodes for solid oxide fuel cells
J.-H. Kim and A. Manthiram*
Solid State Ionics, 180, 1478-1483 (2009). -
High Temperature Crystal Chemistry and Oxygen Permeation Properties of the Mixed Ionic Electronic Conductors LnBaCo2O5+δ (Ln = lanthanide)
J.-H. Kim, L. Mogni, F. Prado, A. Caneiro, J.A. Alonso, A. Manthiram*
Journal of the Electrochemical Society, 156 (12), B1376-B1382 (2009). -
LnBaCo2O5+δ oxides as cathode for intermediate-temperature solid oxide fuel cells
J.-H. Kim and A. Manthiram*
Journal of the Electrochemical Society, 155 (4), B385-B390 (2008). -
Characterization of GdBa1-xSrxCo2O5+δ (0≤ x ≤1) double perovskites as cathodes for solid oxide fuel cells
J.-H. Kim, F. Prado, and A. Manthiram*
Journal of the Electrochemical Society, 155 (10), B1023-B1028 (2008). -
Co-synthesis of nano-sized LSM-YSZ composites with enhanced electrochemical property
J.-H. Kim, R.-H. Song*, J.-H. Kim, T.-H. Lee, Y.-K. Sun, and D.-R. Shin
Journal of the Solid State Electrochemistry, 11 (10), 1385-1390 (2007).